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Category: chemistry – Page 162

A study, published in PNAS Nexus, describes a fabric that can be modulated between two different states to stabilize radiative heat loss and keep the wearer comfortable across a range of temperatures.

Po-Chun Hsu, Jie Yin, and colleagues designed a made of a layered semi-solid electrochemical cell deployed on nylon cut in a kirigami pattern to allow it to stretch and move with the wearer’s body. Modern clothes are made with a variety of insulating or breathable fabrics, but each fabric offers only one thermal mode, determined by the fabric’s emissivity: the rate at which it emits .

The in the fabric can be electrically switched between two states—a transmissive dielectric state and a lossy metallic state—each with different emissivity. The fabric can thus keep the wearer comfortable by adjusting how much body heat is retained and how much is radiated away. A user would feel the same skin temperature whether the external temperature was 22.0°C (71.6°F) or 17.1°C (62.8°F). The authors call this fabric a “wearable variable-emittance device,” or WeaVE, and have configured it to be controlled with a .

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Researchers at the University of Chemistry and Technology in Prague have made progress in the field of assistive technology with the development of a novel auditory human–machine interface using black phosphorus–based tactile sensors. Research led by Prof. Martin Pumera and Dr. Jan Vyskočil has the potential to revolutionize communication for visually or speech-disabled individuals by providing an intuitive and efficient means of conveying information.

Assistive technology that utilizes has traditionally been employed by individuals with or speech and language difficulties. In this study, the focus was on creating an auditory that utilizes audio as a platform for communication between disabled users and society. The researchers developed a piezoresistive tactile sensor using a composite of black phosphorus and polyaniline (BP@PANI) through a simple chemical oxidative polymerization process on cotton fabric.

The unique structure and superior electrical properties of black phosphorus, combined with the large surface area of the fabric, enabled the BP@PANI-based tactile sensor to exhibit exceptional sensitivity, low-pressure sensitivity, reasonable response time, and excellent cycle stability. To demonstrate the real-world application, a was created, incorporating six BP@PANI corresponding to braille characters. This device can convert pressed text into audio, aiding visually or speech-disabled individuals in reading and typing. It offers a promising solution for improving communication and accessibility for this demographic.

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Exploring Mitochondrial Bioenergetics, Optogenetics, Human Health And Aging — Dr. Brandon Berry, Ph.D., University of Washington.

Dr. Brandon Berry, Ph.D. (https://halo.dlmp.uw.edu/people/brandon-berry/) is a postdoctoral researcher in the Kaeberlein Laboratory at University of Washington where his research focuses on how aging and metabolism are linked.

Dr. Berry is interested in how mitochondria, the powerhouses of cells, contribute to and modulate functional decline that occurs during aging, and he is involved in using novel tools, like optogenetics, to precisely control mitochondria and metabolism with light. Through these types of experiments, he can more precisely determine if mitochondrial dysfunction is a cause or a consequence of metabolic aging and may reveal new ways to understand and impact health.

Dr. Berry has BS in Biochemistry from SUNY Geneseo, and an MS and PhD in Physiology from University of Rochester.

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A group of scientists and engineers that includes researchers from The University of Texas at Austin have created a new class of materials that can absorb low energy light and transform it into higher energy light. The new material is composed of ultra-small silicon nanoparticles and organic molecules closely related to ones utilized in OLED TVs. This new composite efficiently moves electrons between its organic and inorganic components, with applications for more efficient solar panels, more accurate medical imaging and better night vision goggles.

The material is described in a new paper in Nature Chemistry.

“This process gives us a whole new way of designing materials,” said Sean Roberts, an associate professor of chemistry at UT Austin. “It allows us to take two extremely different substances, silicon and , and bond them strongly enough to create not just a mixture, but an entirely new hybrid material with properties that are completely distinct from each of the two components.”

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Cancer remains one of the leading causes of death in the US at over 600,000 deaths per year. Cancers that form solid tumors such as in the breast, brain, or skin are particularly hard to treat. Surgery is typically the first line of defense for patients fighting solid tumors. But surgery may not remove all , and leftover cells can mutate and spread throughout the body. A more targeted and wholistic treatment could replace the blunt approach of surgery with one that eliminates cancer from the inside using our own cells.

Dennis Discher, Robert D. Bent Professor of Chemical and Biomolecular Engineering, and postdoctoral fellow Larry Dooling provide a new approach in targeted therapies for solid tumor cancers in their study, published in Nature Biomedical Engineering. Their therapy not only eliminates cancerous cells, but teaches the to recognize and kill them in the future.

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The disposal of tires represents a significant burden on the environment, so companies like Marangoni developed methods to recycle and reuse old tires. Watch how retreading machines make old tires usable again.

Following is a transcript of the video.

Narrator: When your tire wears out, you take it to a shop where it’s tossed out for a new one. The discarded tire is typically recycled — ground up and chemically broken down to use as a building material in streets or parks. Some companies hope to recycle differently. For years, companies like Marangoni have been saving tire casings, replacing the old tread (the rubber that touches the ground) with new tread in a process called “retreading.” These tires are not only easier to make — they typically take 20% of the energy of creating a new tire — they perform well too, standing up to the same tests that one-use tires are subjected to.

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Carbon nanotubes (CNTs) are considered ideal electrochemical energy storage materials due to their high electrical conductivity, large theoretical surface area, and good chemical stability.

However, CNTs tend to aggregate due to strong van der Waals forces, which reduces their electrochemically active area. This problem is even worse for (SWNTs) due to their high length-to-diameter ratio.

Recently, a joint research team led by Dr. Wang Xiao from the Shenzhen Institute of Advanced Technology (SIAT) of the Chinese Academy of Sciences, Dr. Zhu Sheng from Shanxi University, and Prof. Li Yan from Peking University has encapsulated polyoxometalate guest molecules within SWNTs (with a diameter of approximately 1.4 nm) to enhance the electrochemical energy storage of CNTs.

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Chemical signals from contracting muscles can influence the growth of brain networks, according to new research published in Neuroscience. The study highlights the importance of physical activity to mental health, and the findings could also help contribute to the development of more effective treatments for cognitive disorders such as Alzheimer’s disease.

Previous studies had shown that exercise has significant benefits for cognitive health, even when initiated at late stages in life. Exercise has been associated with long-term changes in the hippocampus, a brain region crucial for learning and memory, including increased neurogenesis, synaptogenesis, and enlarged volume.

However, the specific mechanisms through which exercise produces these changes in the hippocampus were not well understood. By uncovering these mechanisms, the authors behind the new study aim to develop exercise-based treatments for cognitive pathologies that affect the hippocampus, such as Alzheimer’s disease, stress, depression, anxiety, and normal aging.

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The Human Genome Project (HGP), the world’s largest collaborative biological project, was a 13-year effort led by the U.S. government with the goal of generating the first full sequence of the human genome. In 2003, HGP produced a genome sequence that accounted for more than 90% of the human genome and was considered as close to complete as was possible with the technologies of the time. HGP unlocked the door to a vast but unannotated collection of genes.

In the following decades, via experimental studies, researchers painstakingly curated reannotations in the form of biochemical reaction graphs. Though gene set enrichment analysis considers groups within these annotation graphs, it disregards group dependencies.

Researchers from the University of Hawaii at Mānoa John A. Burns School of Medicine (JABSOM) are utilizing data from HGP and making advancements in biochemical reaction network analysis. Their work, published in the May 22, 2023 issue of Patterns, demonstrates their approach and may help predict the effects of rare or indistinct genetic variations and guide precision medicine (treatment that can use a patient’s own to help fight disease or guide specific therapy).

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Imagine the possibility of life forms on other planets that don’t resemble any on Earth. What might they look like, and why would they be so different?

Juan Pérez-Mercader says it may be possible and the answer may be that they developed from a different type of . For more than 10 years, the senior research fellow in the Department of Earth & Planetary Sciences and the Origins of Life Initiative at Harvard has studied how to produce synthetic living systems—without relying on biochemistry, or the chemistry that has enabled life on Earth.

“We have been trying to build a non-biochemical system, which unaided is capable of executing the essential properties common to all natural living systems,” Pérez-Mercader explained.

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