Your toilet paper might give you cancer, according to scientists. Experts from the University of Florida warn that your toilet paper could contain toxic “forever chemicals,” also known as per-and polyfluoroalkyl substances (PFAs), which have previously been linked to certain cancers and even low sperm count.
A joint effort in chemistry has resulted in an innovative method for utilizing carbon dioxide in a positive – even beneficial – manner: through electrosynthesis, it is integrated into a series of organic molecules that play a crucial role in the development of pharmaceuticals.
During the process, the team made an innovative discovery. By altering the type of electrochemical reactor used, they were able to generate two distinct products, both of which are useful in medicinal chemistry.
The team’s paper was recently published in the journal Nature. The paper’s co-lead authors are postdoctoral researchers Peng Yu and Wen Zhang, and Guo-Quan Sun of Sichuan University in China.
While tunneling reactions are remarkably hard to predict, a group of researchers were able to experimentally observe such an effect, marking a breakthrough in the field of quantum chemistry.
Tunnel Effect
Predicting tunnel effects is very difficult to pull off. The mechanically exact quantum description of chemical reactions that cover over three particles is quite hard. If it covers over four particles, it is almost impossible to pull off. In order to stimulate the reactions, scientists use classical physics but have to push aside the quantum effects. However, EurekAlert reports that there is a limit to classically describing these chemical reactions. What, then, is the limit?
Tiny insects known as sharpshooters excrete by catapulting urine drops at incredible accelerations. Their excretion is the first example of superpropulsion discovered in a biological system.
Saad Bhamla was in his backyard when he noticed something he had never seen before: an insect urinating. Although nearly impossible to see, the insect formed an almost perfectly round droplet on its tail and then launched it away so quickly that it seemed to disappear. The tiny insect relieved itself repeatedly for hours.
It’s generally taken for granted that what goes in must come out, so when it comes to fluid dynamics in animals, the research is largely focused on feeding rather than excretion. But Bhamla, an assistant professor in the School of Chemical and Biomolecular Engineering at the Georgia Institute of Technology (Georgia Tech), had a hunch that what he saw wasn’t trivial.
Tunneling reactions in chemistry are difficult to predict. The quantum mechanically exact description of chemical reactions with more than three particles is difficult, with more than four particles it is almost impossible. Theorists simulate these reactions with classical physics and must neglect quantum effects. But where is the limit of this classical description of chemical reactions, which can only provide approximations?
Roland Wester from the Department of Ion Physics and Applied Physics at the University of Innsbruck has long wanted to explore this frontier. “It requires an experiment that allows very precise measurements and can still be described quantum-mechanically,” says the experimental physicist. “The idea came to me 15 years ago in a conversation with a colleague at a conference in the U.S.,” Wester recalls. He wanted to trace the quantum mechanical tunnel effect in a very simple reaction.
Since the tunnel effect makes the reaction very unlikely and thus slow, its experimental observation was extraordinarily difficult. After several attempts, however, Wester’s team has now succeeded in doing just that for the first time, as they report in the current issue of the journal Nature.
These peculiar geological structures could explain a long-standing mystery of how Venus loses its heat.
Given Venus and Earth are both rocky planets with roughly the same size and chemistry of their rocks, they should be losing their interior heat to space at a similar rate. How Earth loses its heat is well known, whereas Venus’ flow process remains a mystery.
How does Venus, the hottest planet in the solar system, lose its heat?
NASA/JPL-Caltech/Peter Rubin.
According to a news release from NASA, new research has taken a fresh look at how Venus cools using data from the NASA Magellan mission that spans three decades and discovered that thin parts of the planet’s uppermost layer might provide an answer.
Saad Bhamla was in his backyard when he noticed something he had never seen before: an insect urinating. Although nearly impossible to see, the insect formed an almost perfectly round droplet on its tail and then launched it away so quickly that it seemed to disappear. The tiny insect relieved itself repeatedly for hours.
It’s generally taken for granted that what goes in must come out, so when it comes to fluid dynamics in animals, the research is largely focused on feeding rather than excretion. But Bhamla, an assistant professor in the School of Chemical and Biomolecular Engineering at the Georgia Institute of Technology, had a hunch that what he saw wasn’t trivial.
“Little is known about the fluid dynamics of excretion, despite its impact on the morphology, energetics, and behavior of animals,” Bhamla said. “We wanted to see if this tiny insect had come up with any clever engineering or physics innovations in order to pee this way.”
Water is a vital resource, and clean water is a necessity. Texas A&M University researchers have developed a new technique to monitor one of the key processes of purifying water in real time.
Raw water contains microscopic pathogens that are too small to remove during water and wastewater treatment easily. Chemicals are added to form large clumps called flocs, which are easily filtered out. Flocculation is the process used in water treatment to remove suspended particles from the water.
“Coagulant chemicals need to be added to purify drinking water and remove turbidity (cloudiness) and microbes that are too small to be visible to the naked eye,” said Dr. Kuang-An Chang, professor in the Zachry Department of Civil and Environmental Engineering at Texas A&M.
Chaotic behavior is typically known from large systems: for example, from weather, from asteroids in space that are simultaneously attracted by several large celestial bodies, or from swinging pendulums that are coupled together. On the atomic scale, however, one does normally not encounter chaos—other effects predominate.
Now, for the first time, scientists at TU Wien have been able to detect clear indications of chaos on the nanometer scale—in chemical reactions on tiny rhodium crystals. The results have been published in the journal Nature Communications.
The chemical reaction studied is actually quite simple: with the help of a precious metal catalyst, oxygen reacts with hydrogen to form water, which is also the basic principle of a fuel cell. The reaction rate depends on external conditions (pressure, temperature). Under certain conditions, however, this reaction shows oscillating behavior, even though the external conditions are constant.
Hot gases composed of metal ions and electrons, called plasmas, are widely used in many manufacturing processes, chemical synthesis, and metal extraction from ores and welding. A collaborative research group from Tohoku University and the Toyohashi University of Technology has invented a new and efficient method to create metallic plasmas from solid metals under a strong magnetic field in a microwave resonator. They report their innovation in the journal AIP Advances.
In the most conventional methods for making plasmas, a strong electric field is applied to gases or liquids. This can require enormous amounts of energy. More recently, microwave radiation has also been harnessed to generate plasmas as it converts atoms into a form that can more effectively drive desired chemical processes, among other advantages. The plasmas generated by microwaves are now being used in commercial processes, including semiconductor manufacture, diamond deposition and to release metals from their ores.
Until now, however, this has involved multi-mode microwave generators, which generate a chaotic distribution of microwaves. One key advance achieved by the team is to apply a single-mode microwave generator to produce their metal plasmas. This creates more controlled and highly focused microwaves.
