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Archive for the ‘chemistry’ category: Page 331

Jun 24, 2016

Gun Fusion: Two barrels to the stars

Posted by in categories: chemistry, nuclear energy, particle physics

To start a fusion reaction, you have to create extreme conditions. A combination of stellar temperatures, incredible pressures and lightning-quick energy dumps have all been tried to create these conditions, with varying degrees of success.

In this post, we’ll look at a low-cost, low-energy method of achieving nuclear fusion. It’s not Cold Fusion, it’s Gun Fusion.

Understanding what’s difficult

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Jun 21, 2016

Quantum calculations broaden the understanding of crystal catalysts

Posted by in categories: chemistry, particle physics, quantum physics, supercomputing

Using numerical modelling, researchers from Russia, the US, and China have discovered previously unknown features of rutile TiO2, which is a promising photocatalyst. The calculations were performed at an MIPT laboratory on the supercomputer Rurik. A paper detailing the results has been published in the journal Physical Chemistry Chemical Physics.

It’s all on the surface

Special substances called catalysts are needed to accelerate or induce certain chemical reactions. Titanium dioxide (TiO2) is a good photocatalyst—when exposed to light, it effectively breaks down water molecules as well as hazardous organic contaminants. TiO2 is naturally found in the form of rutile and other minerals. One of the two most active surfaces of rutile R-TiO2 is a surface that is denoted as (011). The photocatalytic activity is linked to the way in which oxygen and titanium atoms are arranged on the surface. This is why it is important to understand which forms the surface of rutile can take.

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Jun 19, 2016

Anti-cancer compound from tree fungus

Posted by in categories: biotech/medical, chemistry

I will be interested in seeing the results after more research done.


A team from the Indian Institute of Science (IISc), Bengaluru, has discovered an anticancer compound, which was isolated from a fungus that can be found in trees and plants. The team from IISc’s biochemistry lab, led by Prof C Jayabaskaran, for over a decade has been working on identification and extraction of natural compounds of pharmaceutical value found in well-known medicinal plants and their fungi. The latest chemical compound discovered is called “Cholestanol glucoside”.

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Jun 13, 2016

Quantum dots may hold key to superior 3D printing materials

Posted by in categories: 3D printing, chemistry, engineering, quantum physics

New research demonstrates that quantum dots solve a key issue with current 3D printing materials. I spoke with Keroles Riad, PhD student at Concordia University Montreal, Quebec, Canada, about his thesis on the photostability of materials used for stereolithography 3D printing. The research was supervised by Prof. Paula Wood-Adams, Prof. Rolf Wuthrich of the Mechanical and industrial engineering department at Concordia and Prof. Jerome Claverie of the Chemistry department at the University of Quebec in Montreal.

While quantum dots have been shown to cure acrylics, Riad says this work is the first demonstration of the process in epoxy resin.

3D printing is often richly rewarding because it spans multiple disciplines. Here we look at a new thesis that advances the critical area of materials. The approach taken uses engineering, chemistry and physics to overcome the issue of stability present in current stereolithography processes. The results could form the basis of superior materials and wider use of 3D printing in many areas.

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May 25, 2016

Engineers take first step toward flexible, wearable, tricorder-like device

Posted by in categories: biotech/medical, chemistry, computing, electronics, engineering, mobile phones, wearables

Engineers at the University of California San Diego have developed the first flexible wearable device capable of monitoring both biochemical and electric signals in the human body. The Chem-Phys patch records electrocardiogram (EKG) heart signals and tracks levels of lactate, a biochemical that is a marker of physical effort, in real time. The device can be worn on the chest and communicates wirelessly with a smartphone, smart watch or laptop. It could have a wide range of applications, from athletes monitoring their workouts to physicians monitoring patients with heart disease.

Nanoengineers and electrical engineers at the UC San Diego Center for Wearable Sensors worked together to build the device, which includes a flexible suite of sensors and a small electronic board. The device also can transmit the data from biochemical and electrical signals via Bluetooth.

Nanoengineering professor Joseph Wang and electrical engineering professor Patrick Mercier at the UC San Diego Jacobs School of Engineering led the project, with Wang’s team working on the patch’s sensors and chemistry, while Mercier’s team worked on the electronics and data transmission. They describe the Chem-Phys patch in the May 23 issue of Nature Communications.

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May 19, 2016

Theorists smooth the way to modeling quantum friction: New paradigm offers a strategy for solving one of quantum mechanics’ oldest problems

Posted by in categories: chemistry, computing, nanotechnology, particle physics, quantum physics

Princeton’s answer to Quantum friction.


Abstract: Theoretical chemists at Princeton University have pioneered a strategy for modeling quantum friction, or how a particle’s environment drags on it, a vexing problem in quantum mechanics since the birth of the field. The study was published in the Journal of Physical Chemistry Letters.

“It was truly a most challenging research project in terms of technical details and the need to draw upon new ideas,” said Denys Bondar, a research scholar in the Rabitz lab and corresponding author on the work.

Quantum friction may operate at the smallest scale, but its consequences can be observed in everyday life. For example, when fluorescent molecules are excited by light, it’s because of quantum friction that the atoms are returned to rest, releasing photons that we see as fluorescence. Realistically modeling this phenomenon has stumped scientists for almost a century and recently has gained even more attention due to its relevance to quantum computing.

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May 17, 2016

Theorists smooth the way to modeling quantum friction

Posted by in categories: chemistry, computing, information science, particle physics, quantum physics

Theoretical chemists at Princeton University have pioneered a strategy for modeling quantum friction, or how a particle’s environment drags on it, a vexing problem in quantum mechanics since the birth of the field. The study was published in the Journal of Physical Chemistry Letters (“Wigner–Lindblad Equations for Quantum Friction”). “It was truly a most challenging research project in terms of technical details and the need to draw upon new ideas,” said Denys Bondar, a research scholar in the Rabitz lab and corresponding author on the work.

Researchers construct a quantum counterpart of classical friction, a velocity-dependent force acting against the direction of motion

Researchers construct a quantum counterpart of classical friction, a velocity-dependent force acting against the direction of motion. In particular, a translationary invariant Lindblad equation is derived satisfying the appropriate dynamical relations for the coordinate and momentum (i.e., the Ehrenfest equations). Numerical simulations establish that the model approximately equilibrates. (© ACS)

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May 11, 2016

Chemists find ‘huge shortcut’ for organic synthesis using C-H bonds

Posted by in category: chemistry

Chemists have taken another major step in the quest to use carbon-hydrogen bonds to create new molecules, a strategy that aims to revolutionize the field of organic synthesis.

The journal Nature is publishing the work by chemists at Emory University. They demonstrated the ability to selectively functionalize the unreactive carbon-hydrogen (C-H) bonds of an alkane without using a directing group, while also maintaining virtually full control of site selectivity and the three-dimensional shape of the produced.

“The catalyst control we have found goes beyond what has been achieved before,” says Huw Davies, an Emory professor of organic chemistry whose lab led the research. “We’ve designed a catalyst that provides a huge shortcut for how chemists can turn a simple, abundant molecule into a much more complex, value-added molecule. We hope this gives people a fundamentally new view of what can be achieved through C-H functionalization.”

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May 9, 2016

Samsung’s Quantum Dot TV Tech to Find Medical Applications

Posted by in categories: bioengineering, chemistry, electronics, food, nanotechnology, quantum physics

Samsung get into the cancer treatment space with their own Q-Dot technology? Another reason for the FDA to show up in tech’s backyard; lookout for all those future federal and state regs & compliance training that will be coming that eats up 20 hours each month of your scientists and engineering talent’s time.


For a lot of users, Samsung might be known best for their smartphones and other mobile devices, but the company is so much more than that. Many of you reading this might have one of Samsung’s Super HD TV sets, a curved Samsung TV or some other model of theirs. Next to smartphones one of their more popular consumer electronics is of course of TVs, and with the advent of new technology such as Quantum Dot, Samsung is getting even better at producing a great image. One area that you might expect to find this Quantum Dot technology being used is for medical uses, but that’s just what researchers have been exploring recently.

Explaining a Quantum Dot can become quite tricky, but to cut a long story short, they are semiconductors that are so small they register at the nanoscale side of things. In terms of Quantum Dots used in television displays, it’s their ability to precisely tune to a specific and exact part of the color spectrum that makes them so attractive, not to mention their much lower power draw. Now, Kim Sung-jee, a professor of the Chemistry department at Pohang University of Science and Technology (POSTECH), has said that “when combining protein which clings to cancer cells and quantum dots, it can be used to seek out cancer cells in the body”. It’s reasoned that the potential for these Quantum Dots to be so precise in terms of color reproduction can help physicians track down certain cancer cells.

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May 7, 2016

An elastomer that behaves like an artificial muscle

Posted by in categories: chemistry, particle physics

(Phys.org)—Animal muscle needs to be strong enough to endure strain; it must also be flexible and elastic; and it is self-healing. Finding a polymer that has all of these properties has proved challenging. However, researchers from Stanford, Nanjing University, UC Riverside, Harvard, and the University of Colorado have reported the synthesis of an elastomer that mimics the properties of animal muscle. Their polymer, is also stable at room temperature and not sensitive to water. Their work appears in Nature Chemistry.

Efforts to create polymers that mimic the properties of biological muscle have come short of being practically useful. Often the bonding involved in making these polymers must be sufficiently strong to serve as actuators, but weak enough for reversible self-healing. Many models, to date, involve hydrogen bonding, but are sensitive to water. Li, et al. have, instead, exploited metal-ligand interactions as a way to mimic muscle properties.

The ligand 2,6-pyridinedicarboxamide (pdca)binds to Fe(III) via the pyridyl nitrogen and the nitrogen and oxygen on the carboxamides. Two pdca molecules coordinate to one Fe(III) atom through six coordination sites. Two of the sites are strong bonds (the pyridyl), two sites are “medium” strength bonds (the amides), and two are weak bonds (the carboxyl). Calculations of bond strength show that the strong bonds are similar to covalent bonds, while the weak Fe-O bonds are similar to hydrogen bonding. This multi-bonding structure, as it turns out, provides an excellent framework for making an elastomer.

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