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Category: chemistry – Page 93

Now Princeton researchers have sparked new life into static. Using millions of hours of computational time to run detailed simulations, the researchers found a way to describe static charge atom-by-atom with the mathematics of heat and work. Their paper appeared in Nature Communications on March 23.

The study looked specifically at how charge moves between materials that do not allow the free flow of electrons, called insulating materials, such as vinyl and acrylic. The researchers said there is no established view on what mechanisms drive these jolts, despite the ubiquity of static: the crackle and pop of clothes pulled from a dryer, packing peanuts that cling to a box.

“We know it’s not electrons,” said Mike Webb, assistant professor of chemical and biological engineering, who led the study. “What is it?”

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Nuclear energy has long been regarded as a next-generation energy source, and major countries around the world are competing to secure cutting-edge technologies by leveraging the high economic efficiency and sustainability of nuclear power. However, uranium, which is essential for nuclear power generation, has serious implications for both soil ecosystems and human health.

Despite being a key radioactive material, uranium poses significant health risks due to its chemical toxicity to the kidneys, bones, and cells. As a result, both the U.S. Environmental Protection Agency and the World Health Organization recommend allowing and advocating for uranium concentrations in wastewater to be below 30 μg/L.

The Korea Institute of Civil Engineering and Building Technology (KICT) has conducted research on a nano-material-based adsorption process to efficiently remove uranium wastewater extracted from actual radioactive-contaminated soil. They have also proposed its applicability to prevent secondary environmental pollutions.

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A QUT-led team of international researchers has made a breakthrough in the development of a type of battery that is much safer and cheaper than the batteries currently charging our smart devices.

The research, published in the Journal of the American Chemical Society, has demonstrated a way of improving the voltage of aqueous zinc-ion batteries, which are a type of rechargeable battery which have a water-based electrolyte.

QUT researchers involved in the study are Professor Ziqi Sun, Associate Professor Dongchen Qi, and Fan Zhang from the School of Chemistry and Physics, Professor Ting Liao and Professor Cheng Yan from the School of Mechanical, Medical and Process Engineering and Dr. Aaron Micallef from the Central Analytical Research Facility.

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EV battery supplier for Tesla, VW and other brands makes huge progress with new LFP power pack.

CATL has announced its new Shenxing Plus battery will be capable of adding as much as 600km of EV range in just 10 minutes, despite relying on cheaper lithium iron phosphate (LFP) chemistry.

That’s up from 400km range over the same timeframe announced by CATL in August last year.

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The same geometric quirk that lets visitors murmur messages around the circular dome of the whispering gallery at St. Paul’s Cathedral in London or across St. Louis Union Station’s whispering arch also enables the construction of high-resolution optical sensors. Whispering-gallery-mode (WGM) resonators have been used for decades to detect chemical signatures, DNA strands and even single molecules.

In the same way that the architecture of a whispering gallery bends and focuses sound waves, WGM microresonators confine and concentrate light in a tiny circular path. This enables WGM resonators to detect and quantify physical and biochemical characteristics, making them ideal for high-resolution sensing applications in fields such as biomedical diagnostics and environmental monitoring.

However, the broad use of WGM resonators has been limited by their narrow dynamic range as well as their limited resolution and accuracy.

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Researchers at EPFL have created the first detailed model explaining the quantum-mechanical effects that cause photoluminescence in thin gold films, a breakthrough that could advance the development of solar fuels and batteries.

Luminescence, the process where substances emit photons when exposed to light, has long been observed in semiconductor materials like silicon. This phenomenon involves electrons at the nanoscale absorbing light and subsequently re-emitting it. Such behavior provides researchers with valuable insights into the properties of semiconductors, making them useful tools for probing electronic processes, such as those in solar cells.

In 1969, scientists discovered that all metals luminesce to some degree, but the intervening years failed to yield a clear understanding of how this occurs. Renewed interest in this light emission, driven by nanoscale temperature mapping and photochemistry applications, has reignited the debate surrounding its origins. But the answer was still unclear – until now.

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It is a common hack to stretch a balloon out to make it easier to inflate. When the balloon stretches, the width crosswise shrinks to the size of a string. Noah Stocek, a PhD student collaborating with Western University physicist Giovanni Fanchini, has developed a new nanomaterial that demonstrates the opposite of this phenomenon.

Working at Interface Science Western, home of the Tandetron Accelerator Facility, Stocek, and Fanchini formulated two-dimensional nanosheets of tungsten semi-carbide (or W2C, a chemical compound containing equal parts of tungsten and carbon atoms) which when stretched in one direction, expand perpendicular to the applied force. This structural design is known as auxetics.

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Dielectric capacitors are ubiquitous components that play a vital role in electronic devices and energy storage systems. Their ability to rapidly discharge significant amounts of energy makes them indispensable for high-power applications.

“High-energy and high-power capacitors are the backbone of reliable power supplies, especially as we transition towards renewable energy sources,” explains Alamgir Karim, Dow Chair and Welch Foundation Professor of Chemical Engineering at UH and a faculty mentor on the project. “However, current dielectric capacitors fall short in terms of energy storage capacity compared to other options like batteries. The advantage of capacitors lies in their superior power density, making them a more suitable choice for various applications.”

The key factor influencing a capacitor’s energy storage is a combination of its permittivity (ε) and dielectric breakdown strength (EBD). Professor Karim emphasizes, “To enhance a capacitor’s energy storage, advancements in both these aspects are crucial.”

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Engineers at Georgia Tech have designed a process that converts carbon dioxide removed from the air into useful raw material that could be used for new plastics, chemicals, or fuels.

Their approach dramatically reduces the cost and energy required for these (DAC) systems, helping improve the economics of a process the researchers said will be critical to addressing .

The key is a new kind of catalyst and electrochemical reactor design that can be easily integrated into existing DAC systems to produce useful carbon monoxide (CO) gas. It’s one of the most efficient such design ever described in , according to lead researcher Marta Hatzell and her team. They have published the details in Energy & Environmental Science.

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Scientists at the Leibniz Institute of Plant Biochemistry (IPB) have succeeded for the first time in stably and precisely inserting large gene segments into the DNA of higher plants very efficiently. To do this, they optimized the gene-editing method CRISPR/Cas, commonly known as “genetic scissors.”

The improved CRISPR method offers great opportunities for the targeted modification of genes in higher plants, both for breeding and research. The study, led by Prof. Alain Tissier and Dr. Tom Schreiber, has been published in Molecular Plant.

CRISPR/Cas is a method with enormous potential for the targeted modification of individual genes. However, this does not apply to all kinds of genetic modifications that breeders and scientists have on their wish lists. While the genetic scissors are ideal for knocking out genes, i.e., switching off or removing existing genes, they do not work well for precisely inserting genes or replacing gene segments. To date, genetic scissors have been too inefficient and therefore of little use for the targeted insertion of genes into the DNA of higher plants.

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