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Category: materials – Page 195

Two teams of researchers have independently found that there exists a certain type of graphene system where electrons freeze as the temperature rises. The first team, with members from Israel, the U.S. and Japan, found that placing one layer of graphene atop another and then twisting the one on top resulted in a graphene state in which the electrons would freeze as temperatures rose. And in attempting to explain what they observed, they discovered that the entropy of the near-insulating phase was approximately half of what would be expected from free-electron spins. The second team, with members from the U.S., Japan and Israel, found the same graphene system and in their investigation to understand their observations, they noted that a large magnetic moment arose in the insulator. Both teams have published their results in the journal Nature. Biao Lian with Princeton University has published a News and Views piece outlining the work by both teams in the same journal issue.

As temperatures around most substances rise, the particles they are made of are excited. This results in solids melting to liquids and liquids turning to a gas. This is explained by thermodynamics—higher temperatures lead to more , which is a description of disorder. In this new effort, both teams found an exception to this rule—a graphene system in which electrons freeze as the .

The graphene system was very simple. Both teams simply laid one sheet of on top of another and then twisted the top sheet very slightly. But it had to be twisted at what they describe as the “magic angle,” describing a twist of just 1 degree. The moiré pattern that resulted led to lower velocity of the electrons in the system, which in turn led to more resistance, bringing the system close to being an insulator.

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Researchers have made unparalleled ultrawide-bandgap semiconductors through temperature and timing, just like baking bread.

Alloying, the process of mixing metals in different ratios, has been a known method for creating materials with enhanced properties for thousands of years, ever since copper and tin were combined to form the much harder bronze. Despite its age, this technology remains at the heart of modern electronics and optics industries. Semiconducting alloys, for instance, can be engineered to optimize a device’s electrical, mechanical and optical properties.

Alloys of oxygen with group III elements, such as aluminum, gallium, and indium, are important semiconductor materials with vast applications in high-power electronics, solar-blind photodetectors and transparent devices. The defining property of a semiconductor is its bandgap, a barrier over which only electrons with the required energy can pass. Beta-phase aluminum gallium oxides are notable because of their relatively large bandgap, but most III-O alloys are expensive to make and of unsatisfactory quality.

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Nature’s strongest material now has some stiff competition. For the first time, researchers have hard evidence that human-made hexagonal diamonds are stiffer than the common cubic diamonds found in nature and often used in jewelry.

Named for their six-sided , hexagonal diamonds have been found at some meteorite impact sites, and others have been made briefly in labs, but these were either too small or had too short of an existence to be measured.

Now scientists at Washington State University’s Institute for Shock Physics created hexagonal diamonds large enough to measure their stiffness using . Their findings are detailed in a recent paper in Physical Review B.

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A pair of researchers with Indiana University and Illinois University, respectively, has developed a theory that suggests crystalizing uranium “snowflakes” deep inside white dwarfs could instigate an explosion large enough to destroy the star. In their paper published in the journal Physical Review Letters, C. J. Horowitz and M. E. Caplan describe their theory and what it could mean to astrophysical theories about white dwarfs and supernovas.

White dwarfs are small stars that have burned up most of their nuclear fuel—they are typically much cooler than they once were and are very dense. In this new effort, Horowitz and Caplan used data from the Gaia space observatory to theorize that sometimes small grains of uranium could begin to crystalize (due to enriched actinides), forming what they describe as snowflakes. They suggest this could happen because of the differing melting points of the material involved. They further suggest that if this were to occur, it could lead to splitting of atomic nuclei, resulting in a series of fission reactions as the solids become enriched in actinides. And if such reactions were to raise the temperature of the interior of the star by igniting carbon, the result would likely be merging of atomic nuclei and eventually a very large fusion reaction that would result in a large explosion—likely large enough to destroy the star.

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“Whooshes of creation” may be producing multiverses at this moment, says astronomer.

The cosmic inflation credited with creating the homogeneous universe which we now enjoy was likely not a one-off event, University of California, Berkeley astronomer Alexei Filippenko, told me. In fact, these ‘whooshes of creation’ may be producing multiverses even at this moment, says Filippenko.

The idea of an exponential, faster-than-light expansion of the early universe, was first put forth by MIT astrophysicist Alan Guth in 1981. And today, Inflation theory is used to explain the Cosmos’ current size, expansion, homogeneity and the fact that it appears to be geometrically flat, I noted in a 2011 issue of Astronomy magazine.

“Inflation happened within the first trillionth of a trillionth of a trillionth of a second of the universe’s existence,” said Filippenko. “It disappeared and then transformed itself into the material that eventually formed us.”

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Radio observations of a cold, dense cloud of molecular gas reveal more than a dozen unexpected molecules.

Scientists have discovered a vast, previously unknown reservoir of new aromatic material in a cold, dark molecular cloud by detecting individual polycyclic aromatic hydrocarbon molecules in the interstellar medium for the first time, and in doing so are beginning to answer a three-decades-old scientific mystery: how and where are these molecules formed in space?

“We had always thought polycyclic aromatic hydrocarbons were primarily formed in the atmospheres of dying stars,” said Brett McGuire, Assistant Professor of Chemistry at the Massachusetts Institute of Technology, and the Project Principal Investigator for GOTHAM, or Green Bank Telescope (GBT) Observations of TMC-1: Hunting Aromatic Molecules. “In this study, we found them in cold, dark clouds where stars haven’t even started forming yet.”

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The recent synthesis of one-dimensional van der Waals heterostructures, a type of heterostructure made by layering two-dimensional materials that are one atom thick, may lead to new, miniaturized electronics that are currently not possible, according to a team of Penn State and University of Tokyo researchers.

Engineers commonly produce heterostructures to achieve new device properties that are not available in a . A van der Waals is one made of 2D materials that are stacked directly on top of each other like Lego-blocks or a sandwich. The van der Waals force, which is an attractive force between uncharged molecules or atoms, holds the materials together.

According to Slava V. Rotkin, Penn State Frontier Professor of Engineering Science and Mechanics, the one-dimensional van der Waals heterostructure produced by the researchers is different from the van der Waals heterostructures engineers have produced thus far.

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For decades, there has been a trend in microelectronics towards ever smaller and more compact transistors. 2D materials such as graphene are seen as a beacon of hope here: they are the thinnest material layers that can possibly exist, consisting of only one or a few atomic layers. Nevertheless, they can conduct electrical currents—conventional silicon technology, on the other hand, no longer works properly if the layers become too thin.

However, such materials are not used in a vacuum; they have to be combined with suitable insulators—in order to seal them off from unwanted environmental influences, and also in order to control the flow of current via the so-called field effect. Until now, hexagonal boron nitride (hBN) has frequently been used for this purpose as it forms an excellent environment for 2D materials. However, studies conducted by TU Wien, in cooperation with ETH Zurich, the Russian Ioffe Institute and researchers from Saudi Arabia and Japan, now show that, contrary to previous assumptions, thin hBN layers are not suitable as insulators for future miniaturized field-effect transistors, as exorbitant leakage currents occur. So if 2D materials are really to revolutionize the , one has to start looking for other insulator materials. The study has now been published in the scientific journal Nature Electronics.

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